To add SQL Server Express 2016 to Windows Server 2012:
Install any Windows updates as normal.
It will indicate there are no more updates to install.
Navigate to: http://www.microsoft.com/en-us/download/details.aspx?id=42153 (install kb2919442)
Run check for updates again.
kb2919355 update will now be available and is a pre=req for SQL Server Express 2016.
Proceed with SQL Server Express 2016 install.